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List Thermochemical Reactions Build-a-Reaction Synthlet

Thermochemistry: Play With Reaction Synthlet


    
   or    Kelvin        
Hydrogenation of 1-butene
           +      
1-Butene
+
Hydrogen
 
Reactants
 
Butane
 
Products
 
Products – Reactants
Δf H ⦵
 
ΔfH⦵
 
Σf-react H ⦵
 
Δf H ⦵
 
 
 
Σf-prod H ⦵
 
Σf-prod H ⦵ - Σf-react H ⦵ = Δr H ⦵
(-0.1 x 1)
+
(0.0 x 1)
=
-0.13
 
(-126.2 x 1)
=
-126.2
 
-126.2 - -0.1 = -126.0 kJmol-1
                             
S ⦵
 
S⦵
 
Σreact S ⦵
 
S ⦵
 
 
 
Σprod S ⦵
 
Σprod S ⦵ - Σreact S ⦵ = Δr S ⦵
(0.306 x 1)
+
(0.131 x 1)
=
0.436
 
(0.310 x 1)
=
0.310
 
0.310 - 0.436 = -0.126 kJK-1mol-1
Gibbs free energy at 298K (standard conditions and standard temperature):
 
Δr G ⦵   = Δr H ⦵ – (T 298 x Δr S ⦵)   =   -126.0– (298 x-0.126)  =
-88.4kJmol-1
Δr H ⦵
=
 -126.0 kJmol-1 Negative value: the reaction is exothermic
Δr S ⦵
=
 -0.126 kJK-1mol-1 Negative value: the system becomes less dispersed
Δr G ⦵ 298K
=
 -88.4 kJmol-1 Negative value: the reaction is feasible (spontaneous)
K eq 298K
=
 3.15 x 10+15 Value is greater than 1: the reaction proceeds to the right
ΔG° = 0.0, and the system is at equilibrium, at a temperature of 999K (726°C)
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List Thermochemical Reactions Build-a-Reaction Synthlet

© Mark R. Leach 1999 –

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