meta-synthesis
About
About meta-synthesis Reviews Products & Services Contact Us FAQs
Our Websites
The INTERNET Database of Periodic Tables The Chemogenesis Web Book The Chemical Thesaurus Chemistry Tutorials & Drills The Truncated Tetrahedron Orange Gate Journal George Truefitt FRIBA Mac Ruff's PNG Sketchbooks MRL's Bow Tuning Page
Web Book Chapters
Web Book Home Page | Chemogenesis Main Index Foreword: Chemogenesis & Chemical Education Part I Atoms | Elements | Periodic Tables 1.1 Introduction to Chemogenesis 1.2 Nucleosynthesis of The Elements 1.3 The Segrè Chart 1.4 Quantum Numbers to Periodic Tables 1.5 The Periodic Table: What Is It Showing? 1.6 The INTERNET Database of Periodic Tables 1.7 Periodicity Part II Structure | Bonding | Material Type 2.1 Mono-Bond Typed Binary Compounds 2.2 Binary Compound Synthlet 2.3 Electronegativity 2.4 van Arkel-Ketelaar Triangles of Bonding 2.5 Tetrahedra of Structure, Bonding & Material Type 2.6 Structure, Bonding & Material Synthlet 2.7 The Classification of Matter: Chemical Stuff Part III Interactions | Reactions | Mechanisms 3.1 The Chemogenesis Analysis: An Overview 3.2 Lewis and Brønsted Models of Acidity 3.3 The Hard Soft [Lewis] Acid Base Principle 3.4 Main Group Elemental Hydrides 3.5 Five Hydrogen Probe Experiments 3.6 Congeneric Dots, Series & Planars 3.7 Quantifying Congeneric Behaviour 3.8 Ligand Replacement Congeneric Series 3.9 Congeneric Array Interactions 3.10 Emergence of Organic Chemistry 3.11 Congeneric Array Database 3.12 The Five Reaction Chemistries 3.13 Lewis Acids & Lewis Bases: A New Analysis 3.14 The Lewis Acid/Base Interaction Matrix 3.15 Patterns in Reaction Chemistry Poster 3.16 Lewis Acid/Base Interaction Matrix Database 3.17 Nucleophiles, Bases & The Fluoride Ion 3.18 Redox Chemistry 3.19 Redox Chemistry Synthlet 3.20 Radical Chemistry 3.21 Diradical Chemistry 3.22 Photochemistry 3.23 Species/Species Interactions 3.24 The Simplest Mechanistic Step: STAD 3.25 Unit & Compound Mechanistic Steps 3.26 The Mechanism Matrix 3.27 Addition To A Double Bond Synthlet 3.28 Pericyclic Reaction Chemistry Part IV Chemical Theory 4.1 Why Do Chemical Reactions Occur? 4.2a Thermochemistry: List Reactions Synthlet 4.2b Thermochemistry: Play With Reaction Synthlet 4.2c Thermochemistry: Bulid A Reaction Synthlet 4.3 Timeline of Structural Theory 4.4 Modern Lewis Theory 4.5 Valence Shell Electron Pair Repulsion: VSEPR 4.6 Diatomic Species by Molecular Orbital Theory 4.7 Polyatomic Species: Molecular Orbitals 4.8 Organic π-Systems 4.9 Functional Group Database Part V Complexity & Emergence 5.1 Chemistry & Complexity: Systems 5.2 Linear Chemistry Systems 5.3 Chemical Systems Prone to Complexity Part VI Extras 6.1 Chemogenesis Videos 6.2 Chemical Thesaurus Reaction Chemistry Database 6.3 Chemogenesis Paper 6.4 Electronegativity as a Basic Elemental Property 6.5 What is Chemistry? (Workshop) 6.6 Literature References & Further Reading

Periodic Table
T-Shirts & more
from the
meta-synthesis

Merch Store

previous

home

next

Lewis Acid/Base Interaction Matrix Database

Type 11 Lewis Acid/Base Complexation Chemistry

Ionic Salts, Proton Transfer or Alkylation

Bonding:

Charge controlled ionic complexes or some type of ligand transfer reaction pathway.

Charge:

The charge on a Type 11 complex is always neutral.

Chemistry:

Onium ions exhibit three types chemistry with Lobe-HOMO Lewis bases:

Ionic salt formation:

[NH₄]⁺ + Cl ^– → NH₄Cl

Proton transfer from the onium ion to lobe-HOMO Lewis base:

[NH₄]⁺ + OH^– → NH₄OH

Alkyl carbenium ion transfer from the onium ion to the lobe-HOMO Lewis base:

[(CH₃)₃O]⁺+ :NR₃ → (CH₃)₂O: + [CH₃–NR₃]⁺

Congeneric Series:

There are many congeneric series and two dimensional congeneric planars, for example the alkyl ammonium halide planar:

	F^–	Cl^–	Br^–	I^–
[NH₄]⁺	[NH₄]⁺F^–	[NH₄]⁺Cl^–	[NH₄]⁺Br^–	[NH₄]⁺I^–
[RNH₃]⁺	[RNH₃]⁺F^–	[RNH₃]⁺Cl^–	[RNH₃]⁺Br^–	[RNH₃]⁺I^–
[R₂NH₂]⁺	[R₂NH₂]⁺F^–	[R₂NH₂]⁺Cl^–	[R₂NH₂]⁺Br^–	[R₂NH₂]⁺I^–
[R₃NH]⁺	[R₃NH]⁺F^–	[R₃NH]⁺Cl^–	[R₃NH]⁺Br^–	[R₃NH]⁺I^–
[R₄N]⁺	[R₄N]⁺F^–	[R₄N]⁺Cl^–	[R₄N]⁺Br^–	[R₄N]⁺I^–

Type 11 Lewis acid/base complex (generic)
	Ammonium acetate more here
	Ammonium bromide more here
	Ammonium chloride more here
	Ammonium fluoride more here
	Ammonium hydrogen difluoride more here
	Ammonium hydrogen sulfide more here
	Ammonium hydrosulfide more here
	Ammonium nitrate more here
	Ammonium nitrite more here
	Ammonium perchlorate more here
	Ammonium sulfate more here
	Ammonium sulfite more here
	Ammonium thiosulfate more here
	Diammonium peroxodisulfate more here
	Oxonium ion/18-Crown-6 Complex more here
	Pyridinium hydrochloride more here
	Triethyloxonium tetrafluoroborate more here
	Trimethylsulfoxonium iodide more here